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I have a number of organic cotton things, and the cotton is very soft and nice. The reasons for supporting organic cotton have already been outlined perfectly, not much to add there. I consider it a real problem that seldom do organic fabrics and fashion meet. In addition to organic cotton, no reason why designers can't use eco-friendly fibers like linen, hemp, and Tencel more.
Patagonia is a good source for organic cotton Ts, although they discontinued my favorite, as well as other stuff. All their cotton is 100% organic. Sundance catalog has organic stuff too, including Ts. Gaiam has nightgowns and sheets.
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