Well... the dress at the CQ awards has an interesting shape, but the color unfortunately washes her out, even with a tan. The color is very particular, it should probably be worn during a day event or perhaps earlier in the season.
The shoes are another terrible story. I love Chanel for many reasons, but I cannot justify wearing most Chanel products before the age of forty or ever, really, in the case of those metallic boots. It's too tough to combine two couture items in the same outfit...
I will give this girl credit for constantly taking risks, though. No one has winning looks all the time and even when she's a bit off she's still got spunk about it. I couldn't name three other fashion icons who would even attempt to pull of the things she frequently does. That's one of the reasons I keep coming back to this thread.