Despite a full day of shooting on the set of Gossip Girl, Leighton Meester (in Versace) was among the famous fans of Donatella Versace who showed up to congratulate the iconic blond on the exclusive launch of Versace menswear at Barneys in New York City. Jonathan Rhys Meyers, Patti LaBelle and Woody Allen were among the cool crowd who toasted the venture on the 3rd floor of the retail mecca before heading downtown to the loft of Barneys CEO Howard Socol for an intimate supper. "I admit I don't really wear men's clothes...at least not in public," joked Meester. "But the collection is amazing and there are some really cute boys here!"